Thursday, March 24, 2011

Measure and Mix for a Better Bond

So now we have touched on what epoxies & polyesters are and their differences, you are all set and ready for gluing. So, you slap a little of the Part A into a cup, put in some of the Part B, stir, and you're off, right?

Is that all there is to it? Are you confident you've achieved the best that the adhesive is capa­ble of delivering? You may be surprised...let's touch upon: mix ratio, and mixing thoroughness.


If you remember in our previous posts, we mentioned one main important difference in epoxies and polyesters is the mix ratio. In a typical polyester system usage is extremely simple: squirt some of the catalyst into the polyester, give it a "lick-­and-a-promise" stir, and you're off! Mix ratios are not critical—use a little catalyst, it cures slowly; use a lot, it cures faster. And the catalyst does not need to be thoroughly mixed in with the polyester; a sloppy stir, and it will still cure just fine.

Epoxies are completely different, however. As is usual when working with a superior product, a little more care is required to achieve the ultimate designed properties. Here, the Part A and Part B MUST be combined in the exact mix ratio specified. Any deviation will adversely affect the ultimate cured properties. Don't be fooled into adding more Part B than recommended to try to speed the cure: it will indeed cure somewhat faster, but the result will be an inferior cure and poor adhesion and strength. And be sure to mix the Part A and B very thoroughly together—the only way to assure complete and proper cure is to be sure the two parts are mixed homogenously. A sloppy stir will result in sloppy cure, producing soft spots as well as "over-cured" and extremely brittle spots.

So pay attention to proper mix ratios and thorough mixing, and you will be rewarded with knowing your epoxy is performing as scientifically engineered to give you a tenacious adhesive bond and long term strength and durability.

Tuesday, March 8, 2011

Structural Adhesives - PART 4, POLYURETHANE

Quick recap – structural adhesives are used in high strength, permanent applications and are able to withstand considerable distress and will not fail at the bonded joint. There are 3 main types: Epoxies, Polyesters and Polyurethanes. Epoxies are high strength and versatile. Unsaturated polyesters are used in the stone industry and are fast curing and low cost. Let us now discuss the third, Polyurethanes.

Polyurethane is any polymer consisting of a chain of organic units joined by urethane links. These polymers are formed through polymerization by reacting a monomer containing at least two isocyanate functional groups with another monomer containing at least two hydroxyl (alcohol) groups in the presence of a catalyst. Whew! In other words - it's a high-tech polymer formed by the reaction between two precursor materials. By adjusting the individual properties of the precursors, an almost limitless variety of polyurethanes can be produced. This flexibility in formulation allows one to custom-engineer the polyurethane to meet the unique demands of the project.

There is a large range of polyurethane adhesive products available. Different chemical combinations result in different properties in polyurethanes. The chemical make-up can be altered to produce different levels of stiffness, density and hardness. All this makes polyurethanes versatile over many industries, such as: automotive, aerospace, construction, textile, wood working, book binding and hardscapes. Out of the three: Polyester, Epoxy and Polyurethane – Polyurethanes are the most flexible (ie: least rigid). Polyurethane, as an adhesive, was first developed in 1985 and has gone through many changes to be the product it is today – especially in cure speed. They are available in one-part or two-part systems. The two part systems require a catalyst.

Benefits of Polyurethanes:

  • Long open time
  • Flexibility
  • Resiliency

Specific uses can be:

  • Aesthetic repairs to stone surfaces
  • Retaining wall capping
  • Subfloor construction
  • PreFab or modular construction
  • Book Binding
  • Binding leather soles to leather and synthetic uppers (shoes)

So, what do you think of these structural adhesives? Which do you prefer to work with and why?

Tuesday, March 1, 2011

Structural Adhesives - Part 3, EPOXY

Let’s quickly recap – structural adhesives are used in high strength, permanent applications and able to withstand considerable magnitude and will not fail at the bonded joint. There are 3 main types Epoxies, Polyesters and Polyurethanes. Unsaturated polyesters are used in the stone industry and are fast curing and low cost.

Epoxy is a copolymer that is formed from two different chemicals - resin and hardener. When these are mixed together, the amine groups react with the epoxide groups to form a bond. This process is called "curing". A strict mix ratio is needed for full cure and cured property retention. If an epoxy is mixed with the incorrect ratio, it may fail.

Epoxies were first introduced commercially in 1946. These high-strength adhesives have a wide range of industry use, such as construction, automotive, aerospace and more. Epoxy adhesives are used where high strength bonds are required.

Epoxies are versatile - as they bond well to many substrates and can be easily modified and developed to suit almost any application. They can be used as adhesives for wood, metal, glass, stone, and some plastics. They can be made flexible or rigid, transparent or colored, fast setting or slow setting.

Epoxies are high strength and have less shrinkage and more chemical resistance than unsaturated polyesters. Epoxies are the structural adhesive that is used primarily in the exterior stone building industry.

Benefits of Epoxies:

  • High strength
  • Excellent durability
  • Extremely versatile
Specific uses can be:
  • Anchor Bolts
  • Buildings – i.e. stone cladding or dimensional stone
  • Boats construction
  • Countertops
  • Golf clubs
  • Surfboards

So, do you use Epoxies in your company? Good or Bad - what are your thoughts? Please tell us your thoughts in the comments section, we'd love to hear from you! * * Stay tuned for the final part of our Structural Adhesives postings as we wrap up with Polyurethanes. * *